Some energy suppliers have been given a three-week deadline to explain accusations they have increased customers' direct debit payments by "more than is necessary".
Jonathan Brearley, boss of the energy regulator Ofgem, recently said there were "troubling signs" of the tactic.
He also expressed concern over customers being directed to inappropriate deals.
Official reviews have now been launched.
Mr Brearley had said in April that reviews were imminent, but the development emerged from an update published on Twitter by Business Secretary Kwasi Kwarteng.
Mr Kwarteng said that some energy companies had been increasing direct debits beyond what was required.
"I can confirm Ofgem has today issued compliance reviews," Mr Kwarteng's tweet went on.
"The regulator will not hesitate to swiftly enforce compliance, including issuing substantial fines."
However, by reviewing the issue, Ofgem has yet to draw a firm conclusion on whether any rules have been broken.
An Ofgem spokesperson said: "Our top priority is to protect consumers and we recently wrote to suppliers to alert them that we are commissioning a series of market compliance reviews to ensure, amongst other things, that they are handling direct debits fairly, and that overall, they are held to higher standards for performance on customer service and protecting vulnerable customers."
A spokesman for Energy UK, which represents energy companies, said: "Suppliers are required to set [direct debits] at a fair and reasonable level based on the customer's individual circumstances, taking into account factors like previous energy use or record with previous payments.
"It is right that the regulator is looking to ensure that suppliers are complying with those requirements. Customers who do have concerns with the level of their direct debit payments should contact their supplier."
Prime Minister Boris Johnson had earlier acknowledged "there is more that we can do" to help families struggling with rising fuel and energy bills.
Opposition parties have called for a windfall tax on energy company profits, with Labour accusing him of offering "no answers" to a "cost of living crisis".
Source: BBC News
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Energy firms face deadline in review of direct debit hikes
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Sam Audley started a blog post Energy firms face deadline in review of direct debit hikes